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Question

Equivalent weight of MnO−4 is equal to molecular weight, when it changes into new species X.


What is X? It is by oxidation or reduction.

A
MnO24 , Reduction
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B
MnO2, Oxidation
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C
Mn2O3, Neither oxidation nor reduction
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D
None of these
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Solution

The correct option is A MnO24 , Reduction
Since equivalent weight is equal to molecular weight, the oxidation state has changed by one unit.

The highest oxidation state of Mn is +7 in MnO4. Hence the oxidation state decreases by one unit to +6.

MnO14MnO24

This represents reduction.

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