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Question

Ethyl alcohol on distillation with X gives chloroform, X is:

A
a paste of bleaching powder
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B
chlorine
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C
methyl chloride
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D
Ca(OH)2
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Solution

The correct option is A a paste of bleaching powder
Bleaching powder, Calcium hypochlorite is an inorganic compound with formula Ca(ClO)₂. As a mixture with lime and calcium chloride, it is marketed as chlorine powder or bleaching powder for water treatment and as a bleaching agent.
Chloroform can be prepared in laboratory by reaction of bleaching powder with ethanol or acetone . In this reaction, bleaching powder acts as oxidising chlorinating and hydrolyzing agent..

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