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Question

Ethyl iodide and n-propyl iodide are allowed to undergo Wurtz reaction. The alkane which will not be obtained in this reaction is:

A
butane
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B
propane
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C
pentane
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D
hexane
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Solution

The correct option is A propane
CH3CH2I+CH3CH2CH2I
(Wurtz reaction) Na
CH3CH2CH2CH3butane+CH3CH2CH2CH2CH2CH3hexane+CH3CH2CH2CH2CH3pentane
Ethyl iodide and n-propyl iodide are allowed to undergo Wurtz reaction and they form butane and hexane as self-addition products and pentane as cross addition product.
So, propane will not be formed.

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