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Question

Experimentally it was found that a metal oxide has formula M0.98O. Metal M is present as M2+ and M3+ in its oxide. Fraction of the metal which exists as M3+ would be :

A
6.05%
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B
5.08%
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C
7.01%
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D
4.08%
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Solution

The correct option is C 4.08%
Average oxidation no. of M=+20098 (lies between 2 and 3)
Let % of M2+ be α and of M3+ be b
or, 2a+3(100a)100=2.04(a+b=100)
2a+3003a=20098
+a=3002.04×100
=300204=96
Thus M2+=96%
M3+=4%

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