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Question

Explain the difference:

a. Diamond and graphite.
b. Crystalline and non-crystalline forms of carbon.

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Solution

a.
Parameter
Diamond
Graphite
Structure Eight sides forming double pyramids. Each carbon atom is held firmly in place by four bonds of neighbouring carbon atoms. Carbon atoms are arranged in flat planes of hexagonal rings, stacked on top of each other.
Nature Colourless and the hardest substance known Soft, greyish and slippery to touch
Refractive index 2.5 Opaque
Specific gravity 3.52 2.53
Conductivity Bad conductor of electricity Good conductor of heat and electricity
Chemical activity Chemically inert under ordinary conditions as there are no free electrons available Slightly more reactive than diamond

b.
Amorphous solids
Crystalline solids
i
They have an irregular shape.
i
They have a definite characteristic geometrical shape.
ii
They have only short-range order in the arrangement of constituent particles.
ii
They have long-range order in the arrangement of constituent particles.
iii
They gradually melt and soften over a range of temperature.
iii
They have sharp and characteristic melting points.
iv
When cut with a sharp-edged tool, they cut into two pieces with irregular shapes.
iv
When cut with a sharp-edged tool, they split into two pieces with plain and smooth newly-generated surfaces.
v
They do not have definite heat of fusion.
v
They have definite and characteristic heat of fusion.
vi
They are isotropic in nature.
vi
They are anisotropic in nature.
vii
They are pseudo solids or super-cooled liquids.
vii
They are true solids.

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