wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

Explain why o-hydroxybenzenaldehyde is liquid at room temperature while p-hydroxybenzenaldehyde has a high melting point

Open in App
Solution

O-hydroxybenzaldehyde (or salicaldehyde) is a liquid at room temperature where as p-hydroxybenzaldehyde is a solid because the former involves intramolecular hydrogen bonding, while in the latter we have intermolecular hydrogen bonding. This intermolecular H-bonding causes association of molecules in p-hydroxybenzaldehyde while there is no such association in o-hydroxybenzaldehyde. As a result, bonding in p-hydroxybenzaldehyde is stronger than in o-hydroxybenzaldehyde and hence it is a solid while o-hydroxybenzaldehyde is a liquid.


flag
Suggest Corrections
thumbs-up
11
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Ideal and Non Ideal Solutions
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon