Suppose a solid with volume V1 at temperature T1 is heated to temperature T2 such that T1 = T2 – T1 is very small.
Let V2 be the volume of the solid at temperature T2. Experimentally, it is found that the increase
in the volume of the solid (volumetric expansion), V2 – V1, is proportional to V1 and ΔT. Therefore, (V2 – V1)α V1ΔT.
∴ V2 – V1 = βV1ΔT, where β is the constant of proportionality, called the volumetric expansion coefficient of the solid.
β = V2−V1 / V1ΔT It is expressed in per °C.
We have V2 = V1 + βV1 ΔT = V1 (1 + βΔT).
is the increase in the volume of a solid per unit original volume per unit rise in its temperature.