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Byju's Answer
Standard XII
Chemistry
Electrometallurgy
Extraction of...
Question
Extraction of aluminium from aluminium oxide
(
A
l
2
O
3
)
is best done by :
A
electrolytic reduction of
A
l
2
O
3
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B
reduction of
A
l
2
O
3
with carbon
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C
reduction of
A
l
2
O
3
wilh sodium
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D
reduction of
A
l
2
O
3
with CO
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Solution
The correct option is
A
electrolytic reduction of
A
l
2
O
3
Aluminum metal is obtained by the electrolysis of fused alumina.
In this process,
fused cryolite
and fluorspar are added to alumina and the mixture melts at 900°C and alumina becomes a good conductor
of electricity.
Here, metallic Al is liberated at the cathode.
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Similar questions
Q.
Extraction of aluminium from oxide
(
A
l
2
O
3
)
is best done by:
Q.
Assertion :In the electrolytic reduction of
A
l
2
O
3
cryolite is used. Reason: Cryolite is an ore of aluminium.
Q.
The Gibb's energy for the decomposition of
A
l
2
O
3
at
500
0
C
is as follows :
2
3
A
l
2
O
3
⟶
4
3
A
l
+
O
2
,
△
r
G
=
+
960
k
J
m
o
l
−
1
The potential difference needed for the electrolytic reduction of aluminium oxide
(
A
l
2
O
3
)
at
500
0
C
at least:
Q.
Assertion :Al obtained only by electrolytic reduction of Alumina (pure) Reason: Aluminium metal has a strong affinity for oxygen and the oxide of Al is
A
l
2
O
3
, which is a very stable oxide. Hence ordinary chemically reducing agents are not sufficient to reduce
A
l
2
O
3
to Al.
Q.
The Gibbs' energy for the decomposition of
A
l
2
O
3
at
500
o
C
is as follows:
2
3
A
l
2
O
3
→
4
3
A
l
+
O
2
;
Δ
G
=
+
966
k
J
m
o
l
−
1
.
The potential difference needed for the electrolytic reduction of aluminium oxide
(
A
l
2
O
3
)
at
500
o
C
is at least:
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