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Question

Figure shows two processes A and B on a system. Let ΔQ1 and ΔQ2 be the heat given to the system in processes A and B respectively. Then
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A
ΔQ1>ΔQ2
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B
ΔQ1=ΔQ2
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C
ΔQ2<ΔQ2
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D
ΔQ1<=ΔQ2
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Solution

The correct option is A ΔQ1>ΔQ2
Both the processes A and B have common initial and final points. So, change in internal energy, ΔU is same in both cases. Internal energy is the state function that does not depend on the path forward.

In the PV diagram, the area under the curve represents the work done on the system, ΔW. Since area under curve A> area under curve B

ΔW1>ΔW2

Now,

ΔQ1=ΔU+ΔW1

ΔQ2=ΔU+ΔW2

But

ΔW1>ΔW2

ΔQ1>ΔQ2

Here, ΔQ1 and ΔQ2 denotes the heat given to the system in processes A and B, receptively.


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