The correct option is B to talk
The infinitive verb is a verb with the word 'to' in front of it. This verb is always just a verb. There is no - ed, no - ing, no - s at the end of the verb. To-infinitive is used to make judgement or comment about the noun. Here, 'She' is a noun. Thus, options A, C, D and E are wrong according to the rule. The correct option is B since 'to' is in front of the verb 'talk' and comment is made for noun.