In the complex K3[Fe(CN)6] K(Potassium) is Alkaline metal with +1 oxidation state,then for the K3 it's +3. CNis a Negative ligand ,for CN6 it's -6
Let, oxidation state of Fe will be x.
The total oxidation state will be zero.
∴3+x+−6=0
∴x=+3
thus the oxidation state of Fe is +3.