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Curtius and Hofmann Rearrangements

Find the majo...

Question

Find the major product when the above compound is made to react with the following reagent.

$B r_{2} ⟶ K O H$ ?

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Solution

Hoffman-bromamide degradation amide on reaction with $B r_{2}$ with $K O H$ gives amine as a product.

Here the intermediate is nitrene.

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Curtius and Hofmann Rearrangements

Standard XII Chemistry

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