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Chelation

Find the numb...

Question

Find the number of ligands (s) which are monodentate, neutral as well as a non-classical ligand.

[ $C O$ , $C N^{-}$ , $S_{2} O_{3}^{2 -}$ , $P F_{3}$ ]

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Solution

The number of ligand(s) which are monodentate, neutral as well as non-classical ligand is 2. These include CO, and PF $_{3}$ .
They are pi bonding ligands.
They form complexes only with transition metals by simultaneous donor and acceptor interaction between occupied and free orbitals of the pi ligand and the d orbitals of the metal.

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π

π

_{3}

_{3}

_{3}

_{5}^{Θ}

_{5}

_{5}^{Θ}

C O, N O, C_{2} H_{4}, C

_{3}

_{5}^{-}

H^{-}

N H_{2}^{-}

O H^{-}

O_{2}^{-}

N O_{2}^{-}, C O_{3}^{2 -}, C l^{-}, C H_{3} C O O^{-}, e n, S O_{4}^{2 -}, N_{2}^{-}

P + Q - R - S "

Θ C

_{2}

_{3}^{2 -}

_{3}

_{5}^{Θ}

_{2}

_{5}^{Θ}

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