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Question

Find the pH of an equimolar solution of HCN and NH4OH.
Given: Ka(HCN)=6×1010 Kb(NH4OH)=1.8×105

A
8.45
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B
4.74
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C
12.5
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D
9.24
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Solution

The correct option is D 9.24
pKa=log(Ka)pKa=log(6×1010)=(100.78)pKa=9.22

pKb=log(Kb)pKb=log(1.8×105)=(50.26)pKb=4.74

For a salt of weak acid and weak base pH is given as:
pH=7+12(pKapKb)pH=7+12(9.224.74)pH=7+4.482pH=9.24

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