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Question

Following are the configuration of 4 atoms.
P=[Ne]3s23p3
Q=[Ar]3d104s24p3
R=[He]2s22p5
S=[Ne]3s1
Incorrect statement is:

A
EA : Q > R[EA = electron affinity]
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B
EN : R > P[EN = electronegative]
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C
IP : P > S [IP = Ionisation potential]
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D
Size : S > R
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Solution

The correct option is A EA : Q > R[EA = electron affinity]
Q=[Ar]3d104s24p3
R=[He]2s22p5
EA:Q>R [EA=Electron Affinity]
Q has stable half filled electronic configuration and to add an e is difficult whereas EA of R will be more than Q as R requires only one more e to complete its' p orbital, hence is more liable to add an e and achieve stable electronic configuration.

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