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Byju's Answer
Standard XII
Chemistry
Secondary Cells
For a cell Mg...
Question
For a cell Mg(s) | Mg
2+
(aq) || Ag
+
(aq) | Ag. Calculate the equilibrium constant at 25°C. Also find the maximum work that can be obtained by operating the cell.
E
0
Mg
2
+
/
Mg
=
-
2
.
37
V
,
E
0
(
Ag
+
/
Ag
)
=
0
.
8
V
Open in App
Solution
T
h
e
g
i
v
e
n
c
e
l
l
i
s
M
g
/
M
g
2
+
/
/
A
g
+
/
A
g
T
h
e
c
e
l
l
p
o
t
e
n
t
i
a
l
i
s
E
0
=
E
o
x
0
+
E
R
e
d
0
=
E
M
g
/
M
g
2
+
0
+
E
A
g
+
/
A
g
0
=
-
(
-
2
.
37
)
+
0
.
8
=
=
3
.
17
V
M
a
x
i
m
u
m
w
o
r
k
d
o
n
e
=
∆
G
0
=
-
n
F
E
0
=
-
2
×
96500
×
3
.
17
=
-
611810
J
E
0
=
0
.
0591
n
log
K
log
K
=
n
E
0
0
.
0591
=
2
×
3
.
17
0
.
0591
K
=
A
.
log
(
107
.
27
)
=
1
.
86
×
10
107
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0
Similar questions
Q.
For a cell
M
g
(
s
)
|
M
g
2
+
(
a
q
)
|
|
A
g
+
(
a
q
)
|
A
g
, find the maximum work (in kJ) that can be obtained by operating the cell.
E
o
(
M
g
2
+
/
M
g
)
=
−
2.37
V
,
E
o
(
A
g
+
/
A
g
)
=
0.8
V
Q.
For the cell reaction,
M
g
|
M
g
2
+
(
a
q
.
)
∥
A
g
+
(
a
q
.
)
|
A
g
calculate the equilibrium constant at
25
∘
C
and maximum work that can be obtained by operating the cell.
E
∘
M
g
2
+
/
M
g
=
−
2.37
v
o
l
t
and
E
∘
A
g
+
/
A
g
=
+
0.80
v
o
l
t
.
Q.
For the cell
M
g
(
s
)
|
M
g
2
+
(
a
q
)
|
|
A
g
+
(
a
q
)
|
A
g
(
s
)
, calculate the equilibrium constant at
25
o
C and the maximum work that can be obtained during operation of cell.
Given
E
o
M
g
/
M
g
2
+
=
+
2.37
V
and
E
o
A
g
+
/
A
g
=
0.80
V
Q.
For a silver- magnesium voltaic cell,
calculate the maximum useful work that can be obtained by operating the cell.
M
g
2
+
+
2
e
−
→
M
g
(
s
)
;
E
0
=
−
2.37
V
A
g
+
(
a
q
)
+
e
−
→
A
g
(
s
)
;
E
0
=
+
0.80
V
Q.
For the cell
M
g
|
M
g
2
+
|
|
A
g
2
+
|
A
g
. Calculate the equilibrium constant at
25
∘
C
and the maximum work that can be obtained during the operation of the cell.
(Given:
E
∘
M
g
/
M
g
2
+
=
2.37
v
o
l
t
and
E
∘
A
g
2
+
/
A
g
=
0.80
v
o
l
t
).
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