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Byju's Answer
Standard XII
Chemistry
Derivation of Kp and Kc
For a given c...
Question
For a given chemical reaction
A
→
B
at
300
K
the free energy change is
−
49.4
k
J
m
o
l
−
1
and the enthalpy of reaction is
51.4
k
J
m
o
l
−
1
. The entropy change of the reaction is _____
J
K
−
1
m
o
l
−
1
.
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Solution
Δ
G
=
−
49.4
k
J
/
m
o
l
Δ
H
=
51.4
k
J
/
m
o
l
Δ
G
=
Δ
H
−
T
Δ
S
−
49400
=
51400
−
300
Δ
S
Δ
S
=
+
100800
300
=
336
J
K
−
1
m
o
l
−
1
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25
Similar questions
Q.
The enthalpy change for a certain reaction at 300 K is -15.0 Kcal mol
−
1
. The entropy change under these conditions is -7.2 cal K
−
1
mol
−
1
. The free energy change for the reaction and its spontaneous/nonspontaneous character will be:
Q.
For the reaction
N
H
4
C
l
(
S
)
→
N
H
3
(
g
)
+
H
C
l
(
g
)
at
25
0
C, enthalpy change
△
=
+
177
k
J
m
o
l
−
1
and entropy change
△
S
=
+
285
J
K
−
1
m
o
l
−
1
. Calculate free energy change
△
G
at
25
0
C and product whether the reaction is spontaneous or not.
Q.
Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are382.64 kJ mol
−
1
and 145.6 JK
−
1
mol
−
1
, respectively. Standard Gibbs energy change for the same reaction at 298 K is:
Q.
The enthalpy and entropy change for a chemical reaction are
−
2.5
×
10
3
c
a
l
and
7.4
c
a
l
K
−
1
respectively. The reaction at
298
K
is:
Q.
The enthalpy and entropy change for a chemical reaction are
−
2.5
×
1
0
3
cal and
7.4
cal
K
−
1
respectively. Predict the nature of reaction at
298
K.
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Standard XII Chemistry
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