For a reaction mechanism with multiple steps, which of the following is not true about the individual steps?
A
Elementary steps in a multi-step reaction mechanism may be either slow or fast.
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B
Fast elementary steps in a multi-step mechanism reach equilibrium quickly.
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C
Fast elementary steps before the rate-determining step may contain an intermediate.
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D
Fast elementary steps after the rate-determining step may have an effect on the overall rate law.
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Solution
The correct option is A Elementary steps in a multi-step reaction mechanism may be either slow or fast. → Elementary step is a single step reaction, with no experimentally detectable reaction intermediate.