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Question

For an adiabatic irreversible process involving an ideal gas:

A
ΔU=nCvΔT
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B
ΔW=nCvΔT
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C
W=Pext.(V2V1)
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D
ΔU=Pext.(V2V1)
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Solution

The correct options are
A ΔU=Pext.(V2V1)
B ΔU=nCvΔT
D W=Pext.(V2V1)
An adiabatic process is one that occurs without the transfer of heat between a system and its surroundings; energy is transferred only as work.
For an adiabatic irreversible process involving an ideal gas, the correct statements are ΔU=nCvΔT and W=Pext.(V2V1).
The equation W=Pext.(V2V1) refers to the work of expansion against constant external pressure.
Also, ΔU=αnRΔT and αR=CV. Hence,ΔU=nCvΔT

Options A, C, and D are correct.

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