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Question

For the decompostion of the compound, represented as NH2COONH4(s)2NH3(g)+CO2(g); the Kp=2.9×105atm3. If the reaction is started with 1 mol of the compounds, the total pressure at equilibrium woud be:

A
1.94×102atm
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B
5.80×102atm
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C
7.66×102atm
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D
38.8×102atm
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Solution

The correct option is C 5.80×102atm
NH4OCONH2(s)2NH3(g)+CO2 (g)
2x x

Kp=(PNH3)2×(PCO2)

2.9×105=22×x3

x=0.019atm= carbon dioxide pressure

So the pressure for NH3 is twice of that according to chemical equation.

Total pressure =(2×0.0193+0.0193) atm

Total pressure =5.8×102 atm

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