For the decompostion of the compound, represented as NH2COONH4(s)⇌2NH3(g)+CO2(g); the Kp=2.9×10−5atm3. If the reaction is started with 1 mol of the compounds, the total pressure at equilibrium woud be:
A
1.94×10−2atm
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B
5.80×10−2atm
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C
7.66×10−2atm
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D
38.8×10−2atm
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Solution
The correct option is C5.80×10−2atm
NH4OCONH2(s)⇋2NH3(g)+CO2 (g)
2x x
Kp=(PNH3)2×(PCO2)
2.9×10−5=22×x3
x=0.019atm= carbon dioxide pressure
So the pressure for NH3 is twice of that according to chemical equation.