For the following bond cleavages, use curved arrows to show the electron flow and classify each as homolysis or heterolysis.

(i) $C H_{3} O - O C H_{3} \to C H_{3} ∙ O + ∙ O C H_{3}$

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Solution

Homolysis fission: (i)
Heterolysis fission: (ii), (iii) & (iv)

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Similar questions

For the following bond cleavages, use curved-arrows to show the electron flow and classify each as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

(a)

(b)

(c)

(d)

Q. For the following bond cleavages, use curved-arrows to show the electron flow and classify each as homolysis or heterolysis. Identify reactive intermediate products as free radical, carbocation and carbanion.

Q. Classify the reagents shown in bonds in the following equations as nucleophiles or electrophiles. Use curved-arrow notation to show the electron movement.
a.

C H_{3} C O O H + H O^{⊖} \to C H_{3} C O O^{⊖} + H_{2} O

C H_{3} C O C H_{3} + N C^{⊖} \to C H_{3} C (C N) O H C H_{3}

C_{6} H_{6} + C H_{3} ⊖ C O \to C_{6} H_{5} C O C H_{3}

Q. What is the correct order of decreasing stability of the following cations?

I - C H_{3} - * C H - C H_{3}

I I - C H_{3} - * C H - O C H_{3}

I I I - C H_{3} - * C H - C H_{2} - O C H_{3}

Q. What is the correct order of the following carbocations from most stable to least stable?
I)

C H_{3} - \oplus C H - C H_{3}

II)

C H_{3} - \oplus C H - O C H_{3}

III)

C H_{3} - \oplus C H - C H_{2} - O C H_{3}

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For the following bond cleavages, use curved arrows to show the electron flow and classify each as homolysis or heterolysis. (i) CH3O−OCH3→CH3∙O+∙OCH3

Homolysis fission: (i)Heterolysis fission: (ii), (iii) & (iv)

For the following bond cleavages, use curved arrows to show the electron flow and classify each as homolysis or heterolysis.

(i) $C H_{3} O - O C H_{3} \to C H_{3} ∙ O + ∙ O C H_{3}$

Homolysis fission: (i)
Heterolysis fission: (ii), (iii) & (iv)