For the synthesis of ammonia at 300 K : N2(g)+3H2(g)→2NH3(g) Calculate the value of ΔG0 ?
N2
H2
NH3
ΔH0_{f}(Kcal/mole)$
0
0
-10
S0(Cal/K−mole)
40
30
45
A
-8 Kcal
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B
-12 Kcal
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C
-16 Kcal
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D
-20 Kcal
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Solution
The correct option is A -8 Kcal ΔH0R=2×ΔH0f(NH3)−3×ΔH0f(H2)−ΔH0f(N2)=−20Kcal ΔS0R=2×S0(NH3)−3×S0(H2)−S0(N2) =2×45−3×30−40=−40Cal/k ΔG0=ΔH0−TΔS0 =−20−300×(−40)1000=−20+12=−8Kcal