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Question

For the zero order reaction AB+C, initial concentration of 'A' is 0.1 M. If 'A' is 0.08 M after 10 minutes, then the half-life and completion time for the reaction, are respectively:

A
25 and 50 min
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B
50 and 100 min
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C
150 and 300 min
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D
70 and 35 min
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Solution

The correct option is A 25 and 50 min
At the time of completion (tc), the reaction is completed which means [A]t=0

From integrated law for zero order reaction,
[A]t=[A]0Kt.....eqn(1)

Substitute value of [A]t in equation (1),
0=[A]0Ktc

tc=[A]0K

Also we know,
K=[A]0[A]tt
At 10 minutes, [A] = 0.08

K=0.10.0810
K=2×103 M min1

Thus,
tc=[A]0K
tc=0.1 M2×103 M min1

tc=50 min

Also half life period,
t12=[A]02K
t12=0.1 M2×2×103 M min1

t12=25 min

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