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Question

For which among the following equimolar aqueous solutions Van't Hoff factor has the lowest value?

A
Aluminium Chloride
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B
Potassium Sulphate
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C
Ammonium Chloride
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D
Urea
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Solution

The correct option is D Urea
For the aqueous solution of urea, van't Hoff factor has the lowest value.
Urea is non-electrolyte and does not dissociate in aqueous solution. Hence, Van't Hoff factor is 1.
For aluminium chloride AlCl3, i=4

AlCl3Al3++3Cl
For potassium sulphate K2SO4, i=3

K2SO42K++SO24

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