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Question

For which of the following reactions, the degree of dissociation cannot be calculated from the vapour density data
I. 2HI(g)H2(g)+I2(g)
II. 2NH3(g)N2(g)+3H2(g)
III. 2NO(g)N2(g)+O2(g)
IV. PCl5(g)PCl3(g)+Cl2(g)

A
I and III
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B
II and IV
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C
I and II
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D
III and IV
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Solution

The correct option is A I and III
The degree of dissociation cannot be calculated from the vapour density data in reaction I and III Because here the number of moles remains unchanged (Δn=0)before and after reaching equilibrium.

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