For which of the following reactions, the degree of dissociation cannot be calculated from the vapour density data I.2HI(g)⇌H2(g)+I2(g) II.2NH3(g)⇌N2(g)+3H2(g) III.2NO(g)⇌N2(g)+O2(g) IV.PCl5(g)⇌PCl3(g)+Cl2(g)
A
I and III
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B
II and IV
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C
I and II
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D
III and IV
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Solution
The correct option is A I and III The degree of dissociation cannot be calculated from the vapour density data in reaction I and III Because here the number of moles remains unchanged (Δn=0)before and after reaching equilibrium.