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Byju's Answer
Standard XII
Physics
Calorimetry
For which rea...
Question
For which reaction will
Δ
H
=
Δ
U
?
A
H
2
(
g
)
+
B
r
2
(
g
)
→
2
H
B
r
(
g
)
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B
C
(
s
)
+
2
H
2
O
(
g
)
→
2
H
2
(
g
)
+
C
O
2
(
g
)
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C
P
C
l
5
(
g
)
→
P
C
l
3
(
g
)
+
C
l
2
(
g
)
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D
2
C
O
(
g
)
+
O
2
(
g
)
→
2
C
O
2
(
g
)
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Solution
The correct option is
A
H
2
(
g
)
+
B
r
2
(
g
)
→
2
H
B
r
(
g
)
Δ
H
=
Δ
U
+
P
Δ
V
Δ
H
=
Δ
U
+
Δ
n
g
R
T
In only reaction (A) the
Δ
n
g
= 0 and hence
Δ
H
=
Δ
U
Suggest Corrections
0
Similar questions
Q.
Predict
Δ
H
>
Δ
U
or
Δ
H
<
Δ
U
.
a.
C
(
g
r
a
p
h
i
t
e
)
+
O
2
(
g
)
⟶
C
O
2
(
g
)
b.
P
C
l
5
(
g
)
⟶
P
C
l
3
(
g
)
+
C
l
2
(
g
)
Q.
2
H
2
(
g
)
+
O
2
(
g
)
⟶
2
H
2
O
(
g
)
For this reaction relate
Δ
H
and
Δ
U
.
Q.
Equilibrium constants for the following reaction at 1200 K are given.
2
H
2
O
(
g
)
⇋
2
H
2
(
g
)
+
O
2
(
g
)
;
K
1
=
6.4
×
10
−
8
2
C
O
2
(
g
)
⇋
2
C
O
(
g
)
+
O
2
(
g
)
;
K
2
=
1.6
×
10
−
6
The equilibrium constant for the reaction
H
2
(
g
)
+
C
O
2
(
g
)
⇋
C
O
(
g
)
+
H
2
O
(
g
)
at 1200 K will be:
Q.
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
94
k
c
a
l
2
C
O
(
g
)
+
O
2
(
g
)
→
2
C
O
2
(
g
)
;
Δ
H
=
−
135.2
k
c
a
l
The heat of formation of
C
O
(
g
)
is :
Q.
The equilibrium constants for the following reactions at
1400
K
are given:
2
H
2
O
(
g
)
⇌
2
H
2
(
g
)
+
O
2
(
g
)
;
K
1
=
2.1
×
10
−
13
2
C
O
2
(
g
)
⇌
2
C
O
(
g
)
+
O
2
(
g
)
;
K
2
=
1.4
×
10
−
12
Then, the equilibrium constant
K
for the reaction,
H
2
(
g
)
+
C
O
2
(
g
)
⇌
C
O
(
g
)
+
H
2
O
(
g
)
, is:
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