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Question

For XY2(g)XY(g)+Y(g), intially 1 mole each of XY2 and y are present in 10L flask at 500mm.If the equilibrium pressure of XY is 150mm, Kp is?

A
500mm Hg
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B
500mm Hg
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C
300mm Hg
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D
600mm Hg
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Solution

The correct option is B 600mm Hg
XY2(g)XY(g)+Y(g)
1mole 1mole at 500mm
i.e. XY2 & Y have same partial pressure i.e. 250mm.
At equilibrium, PXY2=(250p)mm PXY=(P)mm & PY=(250+p)mm
Given P=150mm is equilibriummm pressure of XY
PXY2=250150=100mm
PY=250+150=400mm
KP=150×400100=600mmHg

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