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Question

Formation of HNO3 when NO2 is dissolved in H2O takes place through various reactions. Select the reaction not observed in this step.

A
NO2+H2OHNO3+HNO2
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B
HNO2H2O+NO+HNO3
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C
Both A and B
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D
None of the above
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Solution

The correct option is D None of the above

Step 1: Ammonia is heated with oxygen.Products formed are nitric oxide (NO) and water as products.

4NH3+5O24NO+6H2O

Step 2: In second step the nitric oxide (NO) is combined with oxygen again to create nitrogen dioxide (NO2).

2NO+O22NO2

Step 3: The nitrogen dioxide is reacted with water to form nitric acid (HNO3)

3NO2+H2O2HNO3+NO

Step 4: The nitric oxide produced with the nitric acid is recycled and combined with oxygen and water to produce a higher concentration of nitric acid (HNO3).

4NO2+O2+2H2O4HNO3

So all of the above reactions are involved in nitric acid preparation.

Hence option D is correct


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