Formation of HNO3 when NO2 is dissolved in H2O takes place through various reactions. Select the reaction not observed in this step.
Step 1: Ammonia is heated with oxygen.Products formed are nitric oxide (NO) and water as products.
4NH3+5O2→4NO+6H2O
Step 2: In second step the nitric oxide (NO) is combined with oxygen again to create nitrogen dioxide (NO2).
2NO+O2→2NO2
Step 3: The nitrogen dioxide is reacted with water to form nitric acid (HNO3)
3NO2+H2O→2HNO3+NO
Step 4: The nitric oxide produced with the nitric acid is recycled and combined with oxygen and water to produce a higher concentration of nitric acid (HNO3).
4NO2+O2+2H2O→4HNO3
So all of the above reactions are involved in nitric acid preparation.
Hence option D is correct