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Question

Fully charged lead storage battery contains 1.5 L of 5 M H2SO4. If 2.5 amp of current is taken from the cell for 965 minutes, then what will be the molarity of remaining H2SO4? Assume that volume of battery fluid to be constant.

A
4 M
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B
3.5 M
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C
2 M
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D
4.25 M
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Solution

The correct option is A 4 M
inleadstoragebattry
massofPbdeposited
w=Zit=mol.wt.nF×it
w=207.2×2.5×965×601×96500
w=310.8g
moleofPbdeposited=310.8207.2=1.5mole
totalmoleofsulphuricacid=5×1.5=7.5mole
moleofsulphuricacidinsolution=7.51.5=6mole
molarityofsulphuricacid=61.5L=4M

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