Fusion of $M n O_{2}$ , with $K O H$ in presence of $O_{2}$ produces a salt $W$ . Alkaline solution of $W$ upon electrolytic oxidation yields another salt $X$ . The manganese containing ions present in $W$ and $X$ , respectively are $Y$ and $Z$ . Correct statement(s) is (are)

In both

Y

and

Z, α - b o n d i n g

occurs between

p - o r b i t a l s

of oxygen and d-orbitals of manganese

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Both

Y

and

Z

are coloured and have tetrahedral shape

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In aqueous acidic solution,

Y

undergoes disproportionation reaction to give

Z

and

M n O_{2}

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Y

is diamagnetic in nature while

Z

is paramagnetic

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Solution

The correct options are
A In both $Y$ and $Z, α - b o n d i n g$ occurs between $p - o r b i t a l s$ of oxygen and d-orbitals of manganese
B Both $Y$ and $Z$ are coloured and have tetrahedral shape
D $Y$ is diamagnetic in nature while $Z$ is paramagnetic
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Similar questions

Q. Fusion of

M n O_{2}

with

K O H

in presence of

O_{2}

produces a salt W. An alkaline solution of W upon electrolytic oxidation yields another salt X. The manganese containing ions present in W and X, respectively, are Y and Z. Correct statement(s) is(are)

Fusion of ${MnO}_{2}$ along with $KOH$ and $O_{2}$ forms $X$ . Electrolytic oxidation of $X$ yields $Y$ . $X$ undergoes disproportionation reaction in acidic medium to ${MnO}_{2}$ and $Y$ . The Manganese in $X$ and $Y$ is in the form $W$ & $Z$ respectively, then