There is one Calcium atom on the left and one Calcium atom on the right so this is balanced.
There is 1 Carbon atom on the left and 1 Carbon atom on the right so this is balanced.
There are 3 Oxygen atoms on the left and 3 Oxygen atoms on the right so this is balanced.
There is 1 hydrogen atom on the left but 2 on the right so this is unbalanced. Therefore we need to balance it by using 2 molecules of HCl
CaCO3+2HCl→CaCl2+H2O+CO2