Reduction with carbon | Electrolytic reduction |
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1. Carbon is a reduction agent. | 1. Electrolysis process is used for reduction. |
2. Oxide of moderately reactive metals (e.g., Zn, Fe, Cu, Ni) are reduced by carbon. | 2. Oxide (and chlorides) of highly reactive metals (e.g., Al, Na, Mg, Ca) are reduced by this process. |
3. In this process, the metal oxide is mixed with carbon (coke) and heated in a furnace. ZnO + C → Zn + CO | 3. In this process,molten metal oxide is electrolysed in an electrolytic cell where the cathode acts as a powerful reducing agent by supplying electrons to reduce metal ions into metal. Al3+ + 3e- (Electrolytic reduction) → Al (Aluminium metal) |