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Question

Give the formula of each of the following coordination entities:
(i) Co3+ ion is bound to one Cl, one NH3 molecule and two bidentate ethylene diamine (en) molecule.
(ii) Ni2+ ion is bound to two water molecules and two oxalate ions.
Write the name and magnetic behavior of each of the above coordination entities. (At. no.: Co = 27, Ni = 28)

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Solution

I) [Co(NH3)(en)2Cl]+2
Name of the compound is amminebis-(ethylenediamine)chlorido cobalt (III) ion. Number of unpaired electron are 4. So, the compound is paramagnetic.
II) [Ni(H2O)2(C2O4)2]2
Name of the compound is diquadoxalato nickelate(II) ion. Number of unpaired electrons are 2. So, the compound is paramagnetic.

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