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Question

Give the products of electrolysis in each case.

(Also, give the ionic equations)

Dil. NaCl solution using Platinum or graphite electrodes.


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Solution

  • Electrolysis is the process of breaking the substance into its constituent parts by passing electricity through it when dissolved in water.
  • Step 1: Reaction involved
  • The reaction that has taken place is
    NaCl(aq)Na+(aq)+Cl-(aq)H2O(l)H+(aq)+OH-(aq)
  • Step 2: Reaction at the Cathode
  • At cathode H+ions are discharged in preference to Na+ions. The reaction will be
    2H+(aq)+2e-2H(aq)2H(aq)H2(g)
  • Step 3: Reaction at the anode
  • At the anode, OH-ions are discharged in preference to Cl-ions. The reaction will be
  • \4OH-(aq)-4e-4OH(aq)4OH(aq)O2(g)+2H2O(l)

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