Give the structures of $c i s - [C o C l_{2} (e n)_{2}]$ and $f a c i a l - [C o (N H_{3})_{3} (N O_{2})_{3}]$ isomers.

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Solution

The structures of required isomers are as shown. In cis isomer, two Cl atoms are adjacent to each other. In fac isomer, three ammonia molecules are on same face of octahedron.

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Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

Draw all the isomers (geometrical and optical) of:
${[C o C l_{2} {(e n)}_{2}]}_{2}^{+}$

${[C o (N H_{3}) C l {(e n)}_{2}]}_{2}^{2 +}$

${[C o {(N H_{3})}_{2} C l_{2} (e n)]}_{2}^{+}$

trans - [N i B r_{2} (P P h_{3})_{2}]

meridional - [C o (N H_{3})_{3} (N O_{2})_{3}]

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