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Question

Given below are the statements about diborane.
(a) Diborane is prepared by the oxidation of NaBH4 with I2.
(b) Each boron atom is in sp2 hybridized state.
(c) Diborane has one bridged 3 centre-2-electron bond.
(d) Diborane is a planar molecule.

The option with correct statement(s) is :

A
(c) only
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B
(a) and (b) only
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C
(c) and (d) only
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D
(a) only
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Solution

The correct option is D (a) only
2NaBH4+I2B2H6+2Nal+H2

In B2H6, B atoms are sp3 hybridised
B2H6 has two bridged 3c2e bonds
B2H6 is non planar

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