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Question

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : LiF is sparingly soluble in water.
Reason R : The ionic radius of Li+ ion is smallest among its group members, hence has least hydration enthalpy.

In the light of the above statements, choose the most appropriate answer from the options given below.

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Solution

LiF is sparingly soluble in water.
The low solubility of LiF in water is due to its high lattice enthalpy (Since Li+ and F are small in size).
Also, due to small size of Li+, its hydration enthalpy is high.
Hence, Assertion is true but Reason is false

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