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Synthesis Using Azide & Gabriel Synthesis

A Given compo...

Question

Given compound (A) upon treatment with $K M n O_{4} / H^{+}$ gives (B), which on heating with ammonia produces (C). (C) on treatment with $B r_{2} / N a O H$ produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of $K O H$ followed by acidification gives (F).

(D) is:

A

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B

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C

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D

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Solution

The correct option is C

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Similar questions

Given compound (A) upon treatment with

K M n O_{4} / H^{+}

gives (B), which on heating with ammonia produces (C). (C) on treatment with

B r_{2} / N a O H

produces (D). Strongly heating (C) produces (E) which on further reatment with ethyl 2-bromoacetate in the presence of

K O H

followed by acidification gives (F).

(F) from the following is:

Q. Treatment of compound O with

K M n O_{4} / H^{+}

gave P, which on heating with ammonia gave Q. The compound Q on treatment with

B r_{2} / N a O H

produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of

K O H

followed by acidification, gave a compound T.

The compound R is:

Q. Treatment of compound O with

K M n O_{4} / H^{+}

gave P, which on heating with ammonia gave Q. The compound Q on treatment with

B r_{2} / N a O H

produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of

K O H

followed by acidification, gave a compound T.

The compound T is:

Q. An organic compound 'A' on treatment with

N H_{3}

gives 'B', which on heating gives 'C'. 'C', when treated with

B r_{2}

in the presence of KOH, produces ethylamine. Compound 'A' is:

Q. An organic compound (A) on treatment with acetic acid in the presence of sulfuric acid produces an ester (B). (A) on mild oxidation gives (C). (C) with 50% KOH followed by acidification with diluted HCI generates (A) and (D). (D) with

{P C I}_{5}

, followed by reaction with ammonia, gives (E). (E) dehydration produces hydrocyanic acid. Identify the compounds (A), (B), (C) (D) and (E). Give chemical equations for the reactions involved :

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Synthesis Using Azide & Gabriel Synthesis

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