The correct option is D 12.3
Since sodium hydroxide is a strong base, it will dissociate completely in an aqueous solution. (α=1).
This means that the concentration of the base will be equal to the concentration of hydroxide ions after the reaction runs to completion[NaOH]=[OH−]
NaOH(aq.)+H2O⇌Na+(aq.)+OH−(aq.)Initial: C 0 0Equilibrium: 0 C C
[OH−]=[NaOH]=C=0.02 MpOH=−log[OH−]pOH=−log(0.02)=−(0.3−2)=1.7pOH+pH=14pH=14−1.7pH=12.3