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Question

Given, standard electrode potentials:
Fe3++3eFe;E=0.036 volt
Fe2++2eFe;E=0.440 volt
The standard electrode potential E for Fe3++eFe2+ is:

A
0.772 volt
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B
0.404 volt
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C
0.440 volt
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D
0.772 volt
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Solution

The correct option is A 0.772 volt
Applying G=nFE

Fe2++2eFe G=2×F×(0.440V)=0.88F....(i)
Fe3++3eFe G=3×F×(0.036V)=0.108F....(ii)

Subtracting eq. (i) from eq. (ii),

Fe3++eFe2+;G=0.108F0.880F

=0.772F

E for the reaction =GnF=(0.772F)1×F=0.772 volt.

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