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Question

Given that :

E0Ag+/Ag=+0.80 VE0Co2+/Co=−0.28 VE0Cu2+/Cu=+0.34 VE0Zn2+/Zn=−0.76 V

Which of the following metal has the highest rate of corrosion ?

A
Ag
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B
Cu
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C
Co
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D
Zn
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Solution

The correct option is D Zn
Metals on corrosion form oxide layer on the surface i.e. gets oxidised.

Ag oxidises to Ag2O .Here oxidation state changes from 0 to +1
Co oxidises to CoO. Here oxidation state changes from 0 to +2
Cu oxidises to CuO. Here oxidation state changes from 0 to +2
Zn oxidises to ZnO. Here oxidation state changes from 0 to +2

The metal which has the highest oxidation potential will form the oxide much faster and thus get corroded most easily.
Since,
E0Zn/Zn2+ is the highest. So, corrosion of Zn is the fastest


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