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Question

Given that Ss+32O2(g)SO3(g)+2xkCal; SO2(g)+12O2(g)SO3(g)+ykCal. Which would be the enthalpy of formation SO2?

A
(2xy)
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B
(2x+y)
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C
(y2x)
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D
2xy
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Solution

The correct option is D (y2x)
Solution:- (C) (y2x)
Given:-
S(s)+32O2(g)SO3(g);ΔH=2xkcal.....(1)
SO2(g)+12O2(g)SO3(g);ΔH=ykcal
SO3(g)SO2(g)+12O2(g);ΔH=ykcal.....(2)
Adding eqn(1)&(2), we have
S(s)+32O2(g)+SO3(g)SO3(g)+SO2(g)+12O2(g);ΔH=[y+(2x)]kcal
S(s)+O2(g)SO2(g);ΔH=(y2x)kcal
Hence the enthalpy of formation SO2(g) will be (y2x)kcal.

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