Given the standard oxidation potentials, Fe+0.4V−−−−→Fe2+(aq.)−0.8V−−−−→Fe3+(aq.) Fe+0.9V−−−−→Fe(OH)20.6V−−−→Fe(OH)3 It is easier to oxidise Fe2+ to Fe3+ in:
A
acidic medium
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B
alkaline medium
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C
neutral medium
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D
both in acidic and alkaline mediums
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Solution
The correct option is B alkaline medium E∘Fe2+/Fe3+ is positive in alkaline solution, therefore, it is easier to oxidise Fe2+ to Fe3+ in alkaline medium.