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Byju's Answer
Standard XII
Physics
Calorimetry
H2g+Cl2g=2HCl...
Question
H
2
(
g
)
+
C
l
2
(
g
)
=
2
H
C
l
(
g
)
;
Δ
H
(
298
K
)
=
−
22.06
kcal. For this reaction,
Δ
U
is equal to:
A
−
22.06
+
2
×
10
−
3
×
298
×
2
kcal
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B
−
22.06
+
2
×
298
kcal
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C
−
22.06
−
2
×
298
×
4
kcal
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D
−
22.06
kcal
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Solution
The correct option is
D
−
22.06
kcal
For a chemical reaction-
Δ
H
=
Δ
E
+
Δ
n
g
R
T
Δ
E
=
Δ
E
−
Δ
n
g
R
T
Δ
E
=
−
22.06
K
c
a
l
As the
Δ
n
g
=
0
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0
Similar questions
Q.
H
2
(
g
)
+
C
l
2
(
g
)
=
2
H
C
l
(
g
)
;
Δ
H
(298K)
=
−
22.06
kcal. For this reaction,
Δ
U
is equal to:
Q.
Given that heat of formation of
A
g
2
O
(
s
)
,
H
C
l
(
g
)
and
H
2
O
(
l
)
are
−
731
,
−
22.06
and
−
68.32
kcal respectively. Also,
A
g
2
O
+
2
H
C
l
(
s
)
⟶
2
A
g
C
l
(
s
)
+
H
2
O
(
l
)
;
Δ
H
=
−
77.61
k
c
a
l
If heat of formation of
A
g
C
l
in kcal is
x
then
−
x
/
100
is (nearest integer)__________.
Q.
The heat of formation HCl(g) from the reaction
H
2
(
g
)
+
C
l
2
(
g
)
→
2
H
C
l
(
g
)
;
Δ
H
=
−
44
kcal is:
Q.
From the given table answer the following questions :
CO(g)
C
O
2
(
g
)
H
2
O
(
g
)
H
2
(
g
)
(
Δ
H
∘
f
)
298
( -kCal / mole )
−
26.42
−
94.05
−
57.8
0
(
Δ
G
∘
f
)
298
( -kCal / mole )
−
32.79
−
94.24
−
54.64
0
S
∘
298
( -Cal / Kmole )
47.3
51.1
?
31.2
Reaction :
H
2
O
(
g
)
+
C
O
(
g
)
⇌
H
2
(
g
)
+
C
O
2
(
g
)
( i )
Δ
r
H
∘
298
( ii )
Δ
r
G
∘
298
( iii )
Δ
r
S
∘
298
( iv )
Δ
r
E
∘
298
( v )
S
∘
298
[
H
2
O
(
g
)
]
Q.
Calculate the standard heat of formation of
C
10
H
8
(naphthalene) if standard heat of combustion of naphthalene is
−
1231.0
k
c
a
l
at
298
K
and standard heats of formation of
C
O
2
(
g
)
and
H
2
O
(
l
)
are
−
94.0
k
c
a
l
and
−
68.4
k
c
a
l
respectively.
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