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Question

H2 gas is liberated at cathode and anode both by electrolysis of the following aq. solution except in:

A
NaH
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B
HCOONa
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C
NaCl
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D
LiH
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Solution

The correct option is D NaCl
In case of NaCl
At anode:
2ClCl2+2e
At cathode:
2H++2eH2
So here, Cl2 liberated at anode.
In other cases, hydrides liberate hydrogen gas at anode and hydrogen ion liberates hydrogen gas at cathode.

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