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Question

H2O2 can be obtained when following react with H2SO4 except with:

A
PbO2
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B
BaO2
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C
Na2O2
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D
KO2
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Solution

The correct option is A PbO2
The reactions of the following compounds with H2SO4 can be given as:-
PbO2+H2SO4PbSO4+O2+H2O
BaO2+H2SO4H2O2+BaSO4
Na2O2+H2SO4Na2SO4+H2O2
2KO2+H2SO4K2SO4+H2O2+O2
From the above reactions, it can be conducted that except PbO2 all the compounds react with H2SO4 to give H2O2 while PbO2 on reacting with H2SO4 gives PbSO4,H2O and O2.

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