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Question

H2SO4 can not be used to prepare HI from KI as ____________.

A
its reaction with KI is very slow.
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B
it oxidises HI to iodine.
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C
it disproportionates HI.
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D
it reduces HI.
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Solution

The correct option is B it oxidises HI to iodine.
H2SO4 is stronger oxidising agent and HI is stronger reducing agent. So H2SO4 oxidises and get reduced to SO2.
KI+H2SO4KHSO4+HI
The reaction proceed further as below:
HI+H2SO4I2+SO2+2H2O
Option B is correct.

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