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Question

HNO2 acts as an oxidant with which one of the following reagent:

A
KMnO4
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B
H2S
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C
K2Cr2O7
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D
Br2
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Solution

The correct option is B H2S
HNO2 acts as both oxidising and reducing agent as the oxidation number of N in nitrous acid is +3, the oxidation number can be either increased or decreased.

Nitrous acid oxidises hydrogen sulphide to sulphur:

H2S+2HNO22H2O+2NO+S

whereas oxidation state increases when reacted with KMnO4,Br2 and nitrous acid acts as the reducing agent in this case.

Hence, the correct option is B

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