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Question

Heat of formation of CH4 is:

If given:

C(s)+O2(g)CO2(g) H=394 kJ

H2(g)+12O2(g)H2O(l) H=284 kJ

CH4(g)+2O2(g)CO2(g)+2H2O(l) H=892 kJ


A

-70 kJ

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B

-16.7 kcal

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C

-244 kJ

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D

-58 kcal

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Solution

The correct options are
A

-70 kJ


B

-16.7 kcal


(A,B)

C(s)+O2(g)CO2(g) H=394 kJ .......(i)

H2(g)+12O2(g)H2O(l) H=284 kJ.......(ii)

CH4(g)+2O2(g)CO2(g)+2H2O(l) H=892 kJ...........(iii)

Adding (i) & (2 ×(ii)) and subtracting (iii) from it,

-394 + (2 ×(284)) + 892

=-70 kJ

1 calorie = 4.18 J

70kJ=16.7kcal.


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