Heat of hydrogenation of cyclohexane is -119KJ and heat of hydrogenation of benzene is 206KJ/mole. Find the resonance energy of benzene.
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Solution
Enthalpy of hydrogentaion of benzene is negative 206 kj/mol Enthalpy of hydrogentaion of cyclohexene = -119 kJ/mol Therefore, calculated enthalpy of hydrogenation of benzene=3(-119 ) = -357 kJ/mol
enthalpy of hydrogenation of benzene = -206.kJ/mol
Resonance energy = enthalpy of hydrogentaion of benzene - calculated enthalpy of hydrogenation of benzene. =-206 - (-357) = - 169 kJ/mol